Sustainable and highly controlled aryl couplings revealed by systematic assessment of photoactivatable linkers.
(2022) Sustainable and highly controlled aryl couplings revealed by systematic assessment of photoactivatable linkers. Chem Sci 13(19), 5680-5686. PubMed
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Investigation of new photochemical reactions
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Abstract
The controlled synthesis of biphenyls, which play a prominent role in pharmaceuticals, agrochemicals, and liquid crystals, typically requires hazardous organometallic reagents, aryl halides, and heavy metal catalysts. We recently reported a metal-free, photochemical alternative (
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doi: 10.1039/d2sc00886f PMID: 35694362